Google Chrome is great, easy and fast browser from Google, It’s first browser featured “Most Visited Site”, but there is no official support to themes, plugin add-ons and extensions and doesn’t have more options.
About most visited sites feature , in fact some people don’t like it and try to disable and remove this feature from chrome, may be related with their privacy 
Google Chrome doesn’t have option to automatic disable Most Visited sites list or remove it, now how to disable and remove most visited sites in Google Chrome
Only way (for now) to remove most visited sites in Google Chrome (not permanent and not automatic):
You can remove the most visited sites that are displayed be clearing your history
To disable Most Visited Site in Google Chrome simply using Incognito mode (Ctrl+Shift+N) , and websites visited in Incognito mode won’t be tracked for most visited purposes.
Disable or Remove Most Visited in Chrome feature may be added in upcoming chrome releases.
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